{"id":1852,"date":"2024-01-19T02:18:38","date_gmt":"2024-01-19T02:18:38","guid":{"rendered":"https:\/\/mgg.chem.ucla.edu\/?page_id=1852"},"modified":"2024-01-19T02:19:47","modified_gmt":"2024-01-19T02:19:47","slug":"2011-2021-publications","status":"publish","type":"page","link":"https:\/\/mgg.chem.ucla.edu\/index.php\/2011-2021-publications\/","title":{"rendered":"2011-2021 Publications"},"content":{"rendered":"\n

Publications 2011<\/h2>\n\n\n\n

(165) Kuzmanich, G.; Simoncelli, S.; Gard, M.N.; Sp\u00e4nig, F.; Hoekstra, R.; Guldi, D.M.; Garcia-Garibay, M.A. “Self-Quenching of Benzophenone Excited States in Crystalline Nanoparticles.”<\/strong><\/a> J. Am. Chem. Soc., 2011, 133, 17296\u201317306.<\/p>\n\n\n

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(164) Kuzmanich, G.; Natarajan, A,; Shi, Y.; Patrick, B.O.; Scheffer, J.R.; Garcia-Garibay, M.A. “Stable Radicals During Photodecarbonylations of Trityl-alkyl Ketones Enable Solid State Reactions through Primary and Secondary Radical Centers.”<\/strong><\/a> Photochem. Photobio. Sc., 2011, 10, 1731-1734.<\/p>\n\n\n

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(163) Commins, P.; Nu\u00f1ez, J.E.; Garcia-Garibay, M.A. “Synthesis of Bridged Molecular Gyroscopes with Closed Topologies: Triple One-Pot Macrocyclization.”<\/strong><\/a> J. Org. Chem., 2011, 76, 8355\u20138363.<\/p>\n\n\n

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(162) Morris, W.; Taylor, R.E.; Dybowski, C.; Yaghi, O.M.; Garcia-Garibay, M.A. “Framework Mobility in the Metal-Organic Framework Crystal IRMOF-3: Evidence for Aromatic Ring and Amine Rotation.”<\/strong><\/a> J. Mol. Struct., 2011, 1004, 94\u2013101.<\/p>\n\n\n

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(161) Kuzmanich, G.; Garcia-Garibay, M.A. “Ring strain release as a strategy to enable the singlet state photodecarbonylation of crystalline 1,4-cyclobutanediones.”<\/strong><\/a> J. Phys. Org. Chem., 2011, 23, 376\u2013381.<\/p>\n\n\n

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(160) Kuzmanich, G.; Xue, J.; Netto-Ferreira, J. C.; Scaiano, J. C.; Platz, M.; Garcia-Garibay, M.A. “Steady state and transient kinetics in crystalline solids: the photochemistry of nanocrystalline 1,1,3-triphenyl-3-hydroxy-2-indanone.”<\/strong><\/a> Chem. Sci., 2011, 2, 1497-1501.<\/p>\n\n\n

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(159) Rodriguez-Molina, B.; Farfan, N.; Romero, M.; Mendez-Stivalet, J.M.; Santillan, R.; Garcia-Garibay, M.A. “Anisochronous Dynamics in a Crystalline Array of Steroidal Molecular Rotors: Evidence of Correlated Motion within 1D Helical Domains.”<\/strong><\/a> J. Am. Chem. Soc., 2011, 133, 7280\u20137283.<\/p>\n\n\n

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(158) Shiraki, S.; Natarajan, A.; Garcia-Garibay, M.A. “The Synthesis and Stereospecific Solid-State Photodecarbonylation of Hexasubstituted meso- and d,l-Ketones.”<\/strong><\/a> Photochem. Photobiol. Sci., 2011, 10, 1480-1487.<\/p>\n\n\n

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(157) O’Brien, Z.J.; Natarajan, A.; Khan, S.I.; Garcia-Garibay, M.A. “Synthesis and Solid-State Rotational Dynamics of Crystalline Molecular Gyroscopes with a Robust and Low Density Structure Built with a Phenylene Rotator and a Tri-(meta-terphenyl)methyl Stator.”<\/strong><\/a> Crystal Growth & Design, 2011, 11, 2654-2659.<\/p>\n\n\n

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(156) Lemouchi, C.; Vogelsberg, C.S.; Zorina, L.; Simonov, S.; Batail, P.; Brown, S.; Garcia-Garibay, M.A. “Ultra-fast Rotors for Molecular Machines and Functional Materials via Halogen Bonding: Crystals of 1,4-Bis(iodoethynyl)bicyclo[2.2.2]octane with Distinct Gigahertz Rotation at Two Sites.”<\/strong><\/a> J. Am. Chem. Soc., 2011, 133, 6371\u20136379.<\/p>\n\n\n

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(155) Radhakrishnan, C.; Lo, M.K.F.; Knobler, C.M.; Garcia-Garibay, M.A.; Monbouquette, H.G. “Capping Ligand Effect on the Stability of CdSe Quantum Dot Langmuir Monolayers.”<\/strong><\/a> Langmuir, 2011, 27, 2099-2103.<\/p>\n\n\n

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(154) Kuzmanich, G; Spanig, F.; Tsai, C.K.; Um, J.M.; Hoekstra, R.M.; Houk, K.N.; Guldi, D.M.; Garcia-Garibay, M.A. “Oxyallyl Exposed: An Open Shell Singlet with Picosecond Lifetimes in Solution but Persistent in Crystals of a Cyclobutanedione Precursor.”<\/strong><\/a> J. Am. Chem. Soc., 2011, 133, 2342-2345.<\/p>\n\n\n

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Publications 2012<\/h2>\n\n\n\n

(180) Lo, M.K.F.; Gard, M.N.; Goldsmith, B.R.; Garcia-Garibay, M.A.; Monbouquette, H.G. “Synthesis and Micropatterning of Photocatalytically Reactive Self-Assembled Monolayers Covalently Linked to Si(100) Surfaces via a Si-C Bond.”<\/strong><\/a> Langmuir, 2012, 28, 16156\u201316166.<\/p>\n\n\n

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(179) Czajkowska-Szczykowska, D.; Rodriguez-Molina, B.; Maga\u00f1a-Vergara, N.E.; Santillan, R.; Morzycki, J.W.; Garcia-Garibay, M. A. “Macrocyclic Molecular Rotors with Bridged Steroidal Frameworks.”<\/strong><\/a> J. Org. Chem., 2012, 77, 9970\u20139978.<\/p>\n\n\n

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(178) Shiraki, S.; Vogelsberg, C.S.; Garcia-Garibay, M.A. “Solid-state photochemistry of crystalline pyrazolines: reliable generation and reactivity control of 1,3-biradicals and their potential for the green chemistry synthesis of substituted cyclopropanes.”<\/strong><\/a> Photochem. Photobiol. Sci., 2012, 11, 1929-1937.<\/p>\n\n\n

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(177) Escalante-S\u00e1nchez, E.; Rodr\u00edguez-Molina, B.; Garcia-Garibay, M.A. “Towards Crystalline Molecular Rotors with Linearly Conjugated Diethynyl-Phenylene Rotators and Pentiptycene Stators.”<\/strong><\/a> J. Org. Chem., 2012, 77, 7428\u20137434.<\/p>\n\n\n

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(176) Arcos-Ramos, R.; Rodriguez-Molina, B.; Romero, M.; M\u00e9ndez-Stivalet, J.M.; Ochoa, M.E.; Ram\u00edrez-Montes, P.I.; Santillan, R.; Garcia-Garibay, M.A.; Farfan, N. “Synthesis and Evaluation of Molecular Rotors with Large and Bulky tert-Buthyldiphenylsilyloxy-substituted Trityl Stator.”<\/strong><\/a> J. Org. Chem., 2012, 77, 6887\u20136894.<\/p>\n\n\n

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(175) de Loera, D.; Garcia-Garibay, M.A. “Efficient Aziridine Synthesis in Metastable Crystalline Phases by Photoinduced Denitrogenation of Crystalline Triazolines.”<\/strong><\/a> Org. Lett., 2012, 14, 3874\u20133877.<\/p>\n\n\n

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(174) Stopin, A.; Garcia-Garibay, M. A. “Crystals and Aggregates of a Molecular Tetrarotor with Multiple Trityl Embraces Derived from Tetraphenyladamantane.”<\/strong><\/a> Cryst. Growth Des., 2012, 12, 3792\u20133798.<\/p>\n\n\n

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(173) Morris, W.; Stevens, C. J.; Taylor, R. E.; Dybowski, C.; Yaghi, O.M.; Garcia-Garibay, M.A. “NMR and X-ray Study Revealing the Rigidity of Zeolitic Imidazolate Frameworks (ZIFs).”<\/strong><\/a> J. Phys. Chem. C, 2012, 116, 13307\u201313312.<\/p>\n\n\n

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(172) Garcia-Garibay, M. A. “Advances at the Frontiers of Photochemical Sciences.”<\/strong><\/a> J. Am. Chem. Soc., 2012, 134, 8289\u20138292.<\/p>\n\n\n

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(171) Lemouchi, C.; M\u00e9zi\u00e8re, C.; Zorina, L.; Simonov, S.: Rodr\u00edguez-Fortea, A.; Canadell, E,; Wzietek, P.; Auban-Senzier, P.; Pasquier, C.; Giamarchi, T.; Garcia-Garibay, M.A.; Batail, P. “Design and Evaluation of a Crystalline Hybrid of Molecular Conductors and Molecular Rotors.”<\/strong><\/a>J. Am. Chem. Soc., 2012, 134, 7880\u20137891.<\/p>\n\n\n

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(170) Gard, M.N.; Zucchero, A.J.; Kuzmanich, G.; Oelsner, C.; Guldi, D.; Dreuw, A.; Bunz, U.H.F.; Garcia-Garibay, M.A. “Cruciforms\u2019 Polarized Emission Confirms Disjoint Molecular Orbitals and Excited States.”<\/strong><\/a> Org. Lett., 2012, 14, 1000\u20131003.<\/p>\n\n\n

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(169) Vogelsberg, C.S.; Bracco, S.; Beretta, M.; Comotti, C.; Sozzani, P.; Garcia-Garibay, M.A. “Dynamics of Molecular Rotors Confined in Two Dimensions: Transition from a 2D Rotational Glass to a 2D Rotational Fluid in a Periodic Mesoporous Organosilica.”<\/strong><\/a> J. Phys. Chem. B., 2012, 116, 1623\u20131632.<\/p>\n\n\n

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(168) Vogelsberg C S.; Garcia-Garibay, M.A. “Crystalline molecular machines: Function, phase order, dimensionality, and composition.”<\/strong><\/a> Chem. Soc. Rev., 2012, 41, 1892-1910.<\/p>\n\n\n

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(167) Kuzmanich, G.; Vogelsberg C. S.; Maverick, E. F.; Netto-Ferreira, J. C.: Scaiano, J. C.; Garcia-Garibay, M.A. “Reaction Mechanism in Crystalline Solids: Kinetics and Conformational Dynamics of the Norrish Type II Biradicals from a-Adamantyl p-Methoxyacetophenone.”<\/strong><\/a> J. Am. Chem. Soc., 2012, 134, 1115\u20131123.<\/p>\n\n\n

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(166) Doan, S.C.; Kuzmanich, G.; Gard, M. N.; Garcia-Garibay, M.A.; Schwarts, B.J. “Ultrafast Spectroscopic Observation of a Quantum Chain Reaction: The Photodecarbonylation of Nanocrystalline Diphenylcyclopropenone.”<\/strong><\/a> J. Phys. Chem. Lett., 2012, 3, 81-86.<\/p>\n\n\n

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Publications 2013<\/h2>\n\n\n\n

(186) Tse, L.A.; Stopin, A.; Ganapathi, G,B.; Garcia-Garibay, M.A.; Wirz, R.E. “Thermal Testing of Organic Fluids for Supercritical Thermal Energy Storage Systems.”<\/strong><\/a> Proc. ASME 2013 7th International Conference on Energy Sustainability, ES2013-18195, pp. V001T03A007.<\/p>\n\n\n

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(185) de Loera, D.; Liu, F.; Houk, K. N.; Garcia-Garibay, M.A. “Aziridine Nitrogen Inversion by Dynamic NMR: Activation Parameters in a Fused Bicyclic Structure”<\/strong><\/a> J. Org. Chem<\/em>., 2013<\/strong>, 78<\/em>, 11623-11626.<\/p>\n\n\n

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(184) Rodriguez-Molina, B.; Ochoa, M.E.; Romero, M.; Khan,S.I.; Farfan, N.; Santillan,R.; Garcia-Garibay, M.A. “Conformational Polymorphism and Isomorphism of Molecular Rotors with Fluoroaromatic Rotators and Mestranol Stators.”<\/strong><\/a> Cryst. Growth Des<\/em>., 2013<\/strong>, 13<\/em>, 5107-5115.<\/p>\n\n\n

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(183) Rodriguez-Molina, B.; Perez-Estrada, S.; Garcia-Garibay, M.A. “Amphidynamic Crystals of a Steroidal Bicyclo[2.2.2]octane Rotor: A High Symmetry Group that Rotates Faster than Smaller Methyl and Methoxy Groups.”<\/strong><\/a> J. Am. Chem. Soc<\/em>., 2013<\/strong>, 135<\/em>, 10388\u201310395.<\/p>\n\n\n

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(182) Hughs, M.; Jimenez, M.; Khan,S.I.; Garcia-Garibay, M.A. “Synthesis, Rotational Dynamics, and Photophysical Characterization of a Crystalline Linearly Conjugated Phenyleneethynylene Molecular Dirotor.”<\/strong><\/a> J. Org. Chem<\/em>., 2013<\/strong>, 78<\/em>, 5293\u20135302.<\/p>\n\n\n

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(181) de Loera, D.; Stopin, A.; Garcia-Garibay, M.A. \u201cPhotoinduced and Thermal Denitrogenation of Bulky Triazoline Crystals: Insights into Solid-to-Solid Transformations.\u201d<\/strong><\/a> J. Am. Chem. Soc<\/em>. 2013<\/strong>, 135<\/em>, 6626\u20136632.<\/p>\n\n\n

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Publications 2014<\/h2>\n\n\n\n

(196) Vadehra, G.S.; Maloney, R.P.; Garcia-Garibay, M.A.; Dunn, B. “Naphthalene Diimide Based Materials with Adjustable Redox Potentials: Evaluation for Organic Lithium-Ion Batteries.”<\/a> Chem. Mater.<\/em>, 2014<\/strong>, 26<\/em>, 7151-7157.<\/p>\n\n\n

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(195) Matute, R.A.; Garcia-Garibay, M.A.; Houk, K.N. “Theory of Substituent Effects on the Regioselectivity of Di-\u03c0-methane Rearrangements of Dibenzobarrelenes.”<\/a> Org. Lett.<\/em>, 2014<\/strong>, 16<\/em>, 5232-5234.<\/p>\n\n\n\n

(194) Pearlstein, E.; Hughs, M.; Mazurek, J.; McGraw, K.; Pesme, C.; Garcia-Garibay, M. “Correlations Between Photochemical Damage and UV Fluorescence of Feathers.” ICOM-CC 17th Triennial Conference Preprints, Melbourne, 15\u201319 September 2014, J. Bridgland, Ed., Art. 0406, 8 pp. Paris: International Council of Museums.<\/p>\n\n\n

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(193) Jiang, X.; Rodriguez-Molina, B.; Nazarian, N.; Garcia-Garibay, M.A. “Rotation of a Bulky Triptycene in the Solid State: Towards Engineered Nanoscale Artificial Molecular Machines.”<\/a> J. Am. Chem. Soc.<\/em>, 2014<\/strong>, 136<\/em>, 8871\u20138874.<\/p>\n\n\n

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(192) Staehle I.O.; Rodriguez-Molina, B.; Khan, S.; Garcia-Garibay, M.A. “Engineered Photochromism in Crystalline Salicylidene Anilines by Facilitating Rotation to Reach the Colored trans-Keto Form.”<\/a> Cryst. Growth Des<\/em>., 2014<\/strong>, 14<\/em>, 3667\u20133673.<\/p>\n\n\n

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(191) Lorbach, A.; Maverick, E.; Carreras, A.; Alemany, Pere; Wu, Gang,; Garcia-Garibay M.A; Bazan, G.C. “A Fullerene\u2013Carbene Adduct as a Crystalline Molecular Rotor: Remarkable Behavior of a Spherically-Shaped Rotator.”<\/a> Phys. Chem. Chem. Phys<\/em>., 2014<\/strong>, 16<\/em>, 12980-12986.<\/p>\n\n\n

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(190) Nielsen, A.; Kuzmanich, G.; Garcia-Garibay, M.A. “Quantum Chain Reaction of Tethered Diarylcyclopropenones in the Solid State and Their Distance-Dependence in Solution Reveal a Dexter S2-S2 Energy Transfer Mechanism.“<\/strong><\/a> J. Phys. Chem. A<\/em>, 2014<\/strong>, 118<\/em>, 1858\u20131863.<\/p>\n\n\n

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(189) Islas-J\u00e1come, A.; Guti\u00e9rrez-Carrillo, A.; Garc\u00eda-Garibay, M. A.; Gonz\u00e1lez-Zamora, E. “One-Pot Synthesis of Nuevamine Aza-Analogues by Combined Use of an Oxidative Ugi Type Reaction and Aza-Diels-Alder Cycloaddition.” Synlett<\/em>, 2014<\/strong>, 25<\/em>, 403-406.<\/p>\n\n\n\n

(188) Commins, P.; Garcia-Garibay, M.A. “Photochromic Molecular Gyroscope with Solid State Rotational States Determined by an Azobenzene Bridge.”<\/a> J. Org. Chem<\/em>., 2014<\/strong>, 79<\/em>, 1611\u20131619.<\/p>\n\n\n

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(187) Torres-Huerta, A.; Rodr\u00edguez-Molina, B.; H\u00f6pfl, H.; Garcia-Garibay, M.A. “Synthesis and Solid-State Characterization of Self-Assembled Macrocyclic Molecular Rotors of Bis(dithiocarbamate) Ligands with Diorganotin(IV).”<\/a> Organometallics<\/em>, 2014<\/em>, 33<\/em>, 354\u2013362.<\/p>\n\n\n

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Publications 2015<\/h2>\n\n\n\n

(204) Catalano, L.; P\u00e9rez-Estrada, S.; Terraneo, G.; Pilati, T.; Resnati, G.; Metrangolo, P.; Garcia-Garibay, M.A. “Dynamic Characterization of Crystalline Supramolecular Rotors Assembled through Halogen Bonding”<\/a> J. Am. Chem. Soc.<\/em>, 2015<\/strong>, 137<\/em>, 15386-15389.<\/p>\n\n\n

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(203) Staehle, I.O.; Chung, T.S.; Stopin, A.; Vadehra, G.S.; Hsieh, S.I.; Gibson, J. H.; Garcia-Garibay, M.A. “An Approach to Enhance the Safety Culture of an Academic Research Laboratory by Addressing Behavioral Factors”<\/a> J. Chem. Educ.<\/em>, 2016<\/strong>, 93<\/em>, 217\u2013222<\/p>\n\n\n

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(202) Zhang, K.; Cai, L.; Xing, J.; Garcia-Garibay, M.A.; Kwon, O. “Phosphine-Mediated Iterative Arene Homologation Using Allenes”<\/a> J. Am. Chem. Soc<\/em>., 2015<\/strong>, 137<\/em>, 11258-11261.<\/p>\n\n\n

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(201) Chung, T. S.; Lopes, S.A.; Houk, K.N. “Stereospecific Synthesis of Substituted Aziridines by a Crystal-to-Crystal Photodenitrogenation of \u03942-1,2,3-Triazolines”<\/a> Org. Letters<\/em>, 2015<\/strong>, 17<\/em>, 4568-4571.<\/p>\n\n\n

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(200) Arcos-Ramos, R.; Rodriguez-Molina, B.; Gonzalez-Rodriguez, E.; Ramirez-Montes, P.I.; Ochoa, M.E.; Santillan, R.; Farfan, N.; Garcia-Garibay, M.A. “Crystalline Arrays of Molecular Rotors with TIPS-Trityl and Phenolic-Trityl Stators Using Phenylene, 1,2-Difluorophenylene and Pyridine Rotators.”<\/a> RSC Adv.<\/em>, 2015<\/strong>, 5<\/em>, 55201-55208.<\/p>\n\n\n

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(199) Commins, P.; Natarajan, A.; Tsai, C.; Khan, S.I., Nath, N.K.; Naumov, P.; Garcia-Garibay, M.A. “Structure-Reactivity Correlations and Mechanistic Understanding of the Photoreaarrangement and Photosalient Effect of \u03b1-Santonin and its Derivatives in Solutions, Crystals and Nanocrystalline Suspensions.”<\/a> Cryst. Growth Des.<\/em>, 2015<\/strong>, 15<\/em>, 1983-1990.<\/p>\n\n\n

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(198) Perez-Estrada, S.; Rodriguez-Molina, B.; Xiao, L.; Santillan, R.; Jimenez-Oses, G.; Houk, K.N.; Garcia-Garibay, M.A. “Thermodynamic Evaluation of Aromatic CH\/\u03c0 Interactions and Rotational Entropy in a Molecular Rotor.”<\/a> J. Am. Chem. Soc.<\/em>, 2015<\/strong>, 137<\/em>, 2175-2178.<\/p>\n\n\n

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(197) Hernandez-Linares, M.G.; Guerrero-Luna, G.; Perez-Estrada, S.; Ellison, M.; Ortin, M.; Garcia-Garibay, M.A. “Large-Scale Green Chemical Synthesis of Adjacent Quaternary Chiral Centers by Continuous Flow Photodecarbonylation of Aqueous Suspensions of Nanocrystalline Ketones.”<\/strong><\/a> J. Am. Chem. Soc., 2015, 137(4), 1679-1684.<\/p>\n\n\n

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Publications 2016<\/h2>\n\n\n\n

(208) Jiang, X.; Duan, H.-B.; Khan, S.I.; Garcia-Garibay, M.A, “<\/strong>Diffusion-Controlled Rotation of Triptycene in a Metal-Organic Framework (MOF) Sheds Light on the Viscosity of MOF-Confined Solvent”<\/a> ACS Central Science<\/em>, 2016<\/strong>, 2<\/em>, 608\u2013613<\/p>\n\n\n

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(207) Jiang, X.; O\u2019Brien, Z.J.; Yang, S.; Lai, L.H.; Buenaflor, J.; Tan, C.; Khan, S.; Houk, K.N.; Garcia-Garibay, M.A. “Crystal Fluidity Reflected by Fast Rotational Motion at the Core, Branches and Peripheral Aromatic Groups of a Dendrimeric Molecular Rotor”<\/a> J. Am. Chem. Soc<\/em>., 2016<\/strong>, 138<\/em>, 4650\u20134656.<\/p>\n\n\n

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(206) Anoklase J.-L. Ayitou, A. J.-L.; Flynn, K.; Jockusch, S.; Khan, S.I.; Garcia-Garibay, M.A. “Structure-Kinetics Correlations in Isostructural Crystals of \u03b1-(ortho-tolyl)-Acetophenones: Pinning Down Electronic Effects Using Laser-Flash Photolysis in the Solid State”<\/a> J. Am. Chem. Soc.<\/em>, 2016<\/strong>, 138<\/em>, 2644-2648.<\/p>\n\n\n

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(205) Czajkowska-Szczykowska, D.: Aguilar-Granda, A,; Jadwiga Maj, J.; Wilczewska, A.Z.; Witkowski, S.; Santillan, R.; Miguel A. Garcia-Garibay, M.G.; Morzycki, J.W.; Rodr\u00edguez-Molina, B. “Solid State Characterization of Bridged Steroidal Molecular Rotors: Effect of the Rotator Fluorination on Their Crystallization”<\/a> Cryt. Growth Des.<\/em>, 2016<\/strong>, 16<\/em>, 1599-1605.<\/p>\n\n\n

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Publications 2017<\/h2>\n\n\n\n

Publications for 2017 are listed below. To view earlier publication lists, please select the year from the menu at right.<\/p>\n\n\n\n

(217) Vogelsberg, C.S.; Uribe-Romo, F.J.; Lipton, A.; Yang, S.; Houk, K.N.; Brown, S.; Garcia-Garibay, M.A. \u201cUltrafast Rotations in a MOF Crystalline Material\u201d<\/a> Proc. Nat. Acad. Sci.,<\/em> 2017<\/strong>, Publication Date (Web):<\/strong> December 10, 2017; DOI<\/strong>: 10.1073\/pnas.1708817115<\/p>\n\n\n

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(216) Jin, M.; Chung, T.S.; Seki, T.; Ito, H.; Garcia-Garibay, M.A. \u201cPhosphorescence Control Meditated by Molecular Rotation and Aurophilic Interactions in Amphidynamic Crystals of 1,4-Bis[tri-(p-fluorophenyl)phosphane-gold(I)-ethynyl]benzene<\/a>\u201d J. Am. Chem. Soc,<\/em> 2017<\/strong>, 139<\/em>, 18115\u201318121.<\/p>\n\n\n

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(215) Chung, T.S.; Park, J.H.; Garcia-Garibay, M.A. \u201cTriplet Sensitized Photodenitrogenation of \u03942<\/sup>-1,2,3-Triazolines to form Aziridines in Solution and in the Crystalline State: Observation of the Triplet 1,3-Alkyl-aminyl Biradical\u201d J. Org. Chem.<\/em><\/a>, 2017<\/strong>, 82<\/em>, 12128\u221212133.<\/p>\n\n\n

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(214) Park, J.H.; Hughs, M.; Chung, T.S.; Ayitou, A. J.-L.; Breslin, V.M.; Garcia-Garibay, M.A “Generation and Reactivity Studies of DiarylmethyRadical Pairs in Crystalline Tetraarylacetones via Laser Flash Photolysis Using Nano-crystalline Suspensions\u201d J. Am. Chem. Soc<\/em>. 2017<\/strong>, 139<\/em>, 13312\u201313317.<\/a><\/p>\n\n\n

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(213) Chung, T.S.; Xue, Y.; Carranza, A.; Garcia-Garibay, M.A. “Stereospecific Photochemistry of Delta-2-1,2,3-Triazolines in Solution and in the Solid-State: Scope and Mechanistic Studies\u201d, <\/a>Photochem. & Photobiol. Sc.<\/em>,<\/a> 2017<\/em><\/a><\/strong>, <\/a>16<\/em>, 1458-1463<\/a><\/p>\n\n\n

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(212) Chung, T.S.; Ayitou, A. J.-L.; Park, J. H.; Breslin, V. M.; Garcia-Garibay, M. “Photochemistry and Transmission Pump\u2013Probe Spectros<\/a>copy of 2-Azidobiphenyls in Aqueous Nanocrystalline Suspensions: Simplified Kinetics in Crystalline Solids”<\/a> Phys. Chem. Lett.,<\/em> 2017<\/strong>, 8<\/em>, 1845\u20131850.<\/p>\n\n\n

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(211) Vadehra, G. S.; Jiang, X.; Dotson,J. J.; Chu, G. M.; Garcia-Garibay, M. A. “<\/a>A High Yielding and Divergent Paradigm for the Synthesi<\/a>s of D2h-Symmetric Octakis-Substituted Pentiptycenequinones” Org. Letters,<\/em> 2017,<\/a><\/strong> 19<\/em>, 1838\u20131841<\/a><\/p>\n\n\n

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(210) Breslin, V. M.; Garcia-Garibay, M. A. “<\/a>Transmission Spectroscopy and Kinetics in Crystalline Solids Using Aqueous Nanocrystalline Suspensions: The Spiropyran-Merocyanine Photochromic System” <\/a>Crystal Growth and Design,<\/em> 2017<\/strong>, 7<\/em>, 637\u2013642<\/p>\n\n\n

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(209) Catalano. L.; Perez-Estrada, S.; Wang, H.S.; Ayitou, A. J.-L.; Khan, S.I.; Terraneo, G.; Metrangolo, P.; Brown, S.; Garcia-Garibay, M.A. “<\/a>Rotational Dynamics of Diazabicyclo[2.2.2]octane in Isomorphous Halogen-Bonded Co-crystals: Entropic and Enthalpic Effects<\/a>” J. Am. Chem. Soc.<\/em>, 2017<\/a><\/strong>,<\/a> 139<\/em>, 843\u2013848<\/a><\/p>\n\n\n

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Publications 2018<\/h2>\n\n\n\n

(221) Park, J. H.; Chung, T. S.; Hipwell, V. M.; Rivera, E. A.;  Garcia-Garibay, M. A. “Transient Kinetics and Quantum Yield Studies of Nanocrystalline a-Phenyl-Substituted Ketones: Sorting Out Reactions from Singlet and Triplet Excited States<\/a>,” J. Am. Chem. Soc<\/em>. 2018<\/strong>, 140<\/span><\/em>, 8192\u20138197<\/p>\n\n\n

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(220) Dotson, J. J.;  Perez-Estrada, S.;  Garcia-Garibay, M. A. “Taming Radical Pairs in Nanocrystalline Ketones: Photochemical Synthesis of Compounds with Vicinal Stereogenic All-Carbon Quaternary Centers<\/a>“, J. Am. Chem. Soc<\/em>. 2018<\/strong>,  140<\/em>, <\/span>8359\u20138371<\/p>\n\n\n

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(219) Simonov S.; Zorina, L.; Wzietek, P. Rodr\u00edguez-Fortea, A.; Canadell, E.; M\u00e9zi\u00e8re, C.; Bastien, G.; Lemouchi, C.; Garcia-Garibay, M. A. Batail, P. \u201cStatic Modulation Wave of Halogen-Bond Network Transduced to a Hierarchy of Change Stimuli of Crystalline Rotors Dynamics<\/a>\u201d, Nano Lett<\/em>., 2018<\/strong>, 18<\/em>, 3780\u20133784<\/span><\/p>\n\n\n

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(218) Breslin, V.M.; Barbour, N.A.; Dang,D.-K.; Lopez, S.A.; Garcia-Garibay, M.A., \u201cNanosecond laser flash photolysis of a 6-nitroindolinospiropyran in solution and in nanocrystalline suspension under single excitation conditions<\/a>\u201d, Photochem. Photobiol. Sci.<\/em>, 2018<\/strong>, 17<\/em>, 741 – 749.<\/p>\n\n\n

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Publications 2019<\/h2>\n\n\n\n

(228) Jin, M.; Yamamoto, S.; Seki, T.; Ito, H.; Garcia-Garibay, M. A. “Anisotropic Thermal Expansion as the Source of Macroscopic and Molecular Scale Motion in Phosphorescent Amphidynamic Crystals<\/a>“, Angew. Chem. Int. Ed.<\/em> 2019<\/strong>, 131<\/em>, 18171.
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(227) Jiang, X.; Duan, H.-B.; Jellen, M. J.; Chen, Y.; Chung, T. S.; Liang, Y.; Garcia-Garibay, M. A. “Thermally Activated Transient Dipoles and Rotational Dynamics of Hydrogen-Bonded and Charge-Transferred Diazabicyclo [2.2.2]octane Molecular Rotors<\/a>“, J. Am. Chem. Soc.<\/em> 2019<\/strong>, 141<\/em>, 16802-16809
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(226) Hipwell, V. M.; Garcia-Garibay, M.A. “Mechanistic Studies of Adamantylacetophenones with Competing Reaction Pathways in Solution and in the Crystalline Solid State<\/a>“, J. Org. Chem.<\/em>, 2019<\/strong>, 84<\/em>, 11103-11113
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(225) Colin-Molina, A.; Karothu, D. P.; Jellen, M. J.; Toscano, R. A.; Garcia-Garibay, M. A.; Naumov, P.; and Rodriguez-Molina, B. “Thermosalient Amphidynamic Molecular Machines: Motion at the Molecular and Macroscopic Scales<\/a>“, Matter, <\/em>2019<\/strong>, 1, 1033-1046<\/em>
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(224) Howe, M. E.; Garcia-Garibay, M.A. “Fluorescence and Rotational Dynamics of a Crystalline Molecular Rotor Featuring an Aggregation-Induced Emission Fluorophore<\/a>“,  J. Org. Chem.<\/em>, 2019<\/strong>, 84<\/em>, 9570-9576<\/p>\n\n\n

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(223) Howe, M. E.; Garcia-Garibay, M. A. \u201cThe Roles of Intrinsic Barriers and Crystal Fluidity on the Dynamics of Crystalline Molecular Rotors and Molecular Machines<\/a>\u201d, J. Org. Chem.<\/em> 2019<\/strong>, 84<\/em>, 9835-9849.<\/p>\n\n\n

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(222) Perez-Estrada, S.; Rodr\u00edguez-Molina, B.; Maverick, E.; Khan, S.; Garcia-Garibay, M.A. \u201cThrowing in a Monkey Wrench to Test and Determine Geared Motion in the Dynamics of a Crystalline 1D-Columnar Rotor Array<\/a>“, J. Am. Chem. Soc<\/em>. 2019<\/strong>, 141<\/em>, 2413\u20132420<\/p>\n\n\n

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Publications 2020<\/h2>\n\n\n\n

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(238) Chang, T. Y.; Dotson, J. J.; Garcia-Garibay, M. A.\u201cScalable Synthesis of Vicinal Quaternary Stereocenters via the Solid-State Photodecarbonylation of a Crystalline Hexasubstituted Ketone<\/a>\u201d Org. Lett. <\/em>2020, 22<\/em>, 8855\u20138859<\/p>\n\n\n

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(237) Liepuoniute, I.; Jellen, M. J.; Garcia-Garibay, M. A.\u201cCorrelated motion and mechanical gearing in amphidynamic crystalline molecular machines<\/a>\u201d Chem. Sci. 11<\/em>, 12994\u201313007<\/p>\n\n\n

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(236) Jellen, M. J.; Ayodele M.; Cantu A. <\/strong>L; Forbes, M. D. E.; Garcia-Garibay, M. A.\u201c2D Arrays of Organic Qubit Candidates Embedded into a Pillared-Paddlewheel Metal-Organic Framework<\/a>\u201d J. Am. Chem. Soc.<\/em> 2020<\/strong>, 142<\/em>, 18513\u201318521<\/p>\n\n\n

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(235) Liepuoniute, I.; Huynh, C. M.; P\u00e9rez-Estrada, S.; Wang, Y.; Khan, S. I.; Houk, K. N.; Garcia-Garibay, M. A.\u201cEnhanced Rotation by Ground State Destabilization in Amphidynamic Crystals of a Dipolar 2,3-difluorophenylene Rotator as Established by Solid State 2H NMR and Dielectric Spectroscopy<\/a>\u201d J. Phys. Chem. C<\/em>, 2020<\/strong>, 124<\/em>, 15391\u201315398<\/p>\n\n\n

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(234) Dotson, J. J.; Bachman, L. J.; Garcia-Garibay, M. A.; Garg, N. K. \u201cDiscovery and Total Synthesis of a Bis(Cyclotryptamine) Alkaloid Bearing the Elusive Piperidinoindoline Scaffold<\/a>\u201d J. Am. Chem. Soc.<\/em>, 2020<\/strong>, 142<\/em>, 11685\u201311690<\/p>\n\n\n\n

Featured in JACS Spotlight<\/a><\/strong> <\/p>\n\n\n

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(233) Liepuoniute, I.; Sanders, J. N.; V.; Garcia-Garibay, M. A.; Houk, K. N. \u201cComputational Investigation into Ligand Effects on Correlated Geared Dynamics in Dirhodium Supramolecular Gears \u2013 Insights Beyond the NMR Experimental Window<\/a><\/a>\u201d J. Org. Chem.<\/em>, 2020<\/strong>, 85<\/em>, 8695\u20138701<\/p>\n\n\n

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(232) Howe, M.E.; Barbour, N. A.; Garcia, R. V.; Garcia-Garibay, M. A. \u201cThe Use of Fluorescence Anisotropy Decay to Measure Rotation of Acenes in Viscous Solution<\/a>\u201d J. Org. Chem.<\/em>, 2020<\/strong>, 85<\/em>, 6872\u20136877<\/p>\n\n\n

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(231) Dotson, J. J.; Garg, N. K.; Garcia-Garibay, M. A. Evaluation of the photodecarbonylation of crystalline ketones for the installation of reverse prenyl groups on the pyrrolidinoindoline scaffold<\/a>, Tetrahedron<\/em>, Publication Date:  April 10, 2020. <\/p>\n\n\n

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(230) Jiang, X.; Laffoon, S. D.; Chen, D.; P\u00e9rez-Estrada, S.; Danis, A. S.; Rodr\u00edguez-L\u00f3pez, J.; Garcia-Garibay, M. A.; Zhu, J.; Moore, J. S. Kinetic Control in the Synthesis of a M\u00f6bius Tris((ethynyl)[5]helicene) Macrocycle Using Alkyne Metathesis<\/a>,  J. Am. Chem. Soc.<\/em>,  2020<\/strong>, 142<\/em>, 6493\u20136498<\/p>\n\n\n

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(229)  Jiang, X.; Yang, S.; Jellen, M.J.; Houk, K. N.; Garcia-Garibay, M. A. Molecular Spur Gears with Triptycene Rotators and a Norbornane-Based Stator<\/a>, Org. Lett<\/em> 2020<\/strong>, 22<\/em>, 4049\u20134052 <\/p>\n\n\n

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Publications 2021<\/h2>\n\n\n\n

(244) Liu, Z.; Wang, Y.; Garcia-Garibay, M. A. \u201cRotational Dynamics of an Amphidynamic Zirconium Metal\u2013Organic Framework Determined by Dielectric Spectroscopy<\/a>.\u201d J. Phys. Chem. Lett.<\/em> 2021<\/strong>, 12<\/em>, 5644-5648<\/p>\n\n\n

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(243) Park, J. H.; Hipwell, V. M.; Rivera, E. A.; Garcia-Garibay, M. A. \u201cStrongly Entangled Triplet Acyl\u2013Alkyl Radical Pairs in Crystals of Photostable Diphenylmethyl Adamantyl Ketones<\/a>.\u201d J. Am. Chem. Soc.<\/em> 2021<\/strong>, 143<\/em>, 886\u2013892<\/p>\n\n\n

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(242) Jellen, M. J.; Liepuoniute, I.; Jin, M.; Jones, C. G.; Jiang, X.; Nelson, H. M.; Houk, K. N.; Garcia-Garibay, M. A. \u201cEnhanced Gearing Fidelity Achieved Through Macrocyclization of a Solvated Molecular Spur Gear<\/a>.\u201d J. Am. Chem. Soc.<\/em> 2021<\/strong>, 143<\/em>, 7740\u20137747<\/p>\n\n\n

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(241) Dotson, J. J.; Liepuoniute, I.; Bachman, L. J.; Hipwell, V. M.; Khan, S. I.; Houk, K. N.; Garg, N. K. Garcia-Garibay, M. A. \u201cTaming Radical Pairs in the Crystalline Solid State: Discovery and Total Synthesis of Psychotriadine<\/a>.\u201d J. Am. Chem. Soc.<\/em> 2021<\/strong>, 143<\/em>, 4043\u20134054<\/p>\n\n\n\n

Featured in JACS Spotlight<\/strong><\/a><\/p>\n\n\n\n

Highlighted by UCLA Chemistry & Biochemistry<\/strong><\/a><\/p>\n\n\n

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(240) Su, Y-S., Lamb, E. S., Liepuoniute, I.; Chronister, I.; Stanton, A. L.; Guzman, P.; P\u00e9rez-Estrada, S.; Chang, T. Y.; Houk, K. N.; Garcia-Garibay, M. A.; Brown, S. E. \u201cDipolar order in an amphidynamic crystalline metal\u2013organic framework through reorienting linkers<\/a>\u201d Nat. Chem. <\/em>2021<\/strong>, 13<\/em>, 278\u2013283<\/p>\n\n\n\n

Highlighted by UCLA Chemistry & Biochemistry<\/strong><\/a><\/p>\n\n\n

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(239) Jin, M.; Ando, R.; Jellen, M. J.; Garcia-Garibay, M. A.; Ito, H. \u201cEncapsulating <\/a>N<\/a><\/em>-Heterocyclic Carbene Binuclear Transition-Metal Complexes as a New Platform for Molecular Rotation in Crystalline Solid-State<\/a>\u201d J. Am. Chem. Soc.<\/em> 2021, <\/strong>143<\/em>, 1144\u20131153
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Highlighted by Communications Chemistry<\/strong><\/a><\/p>\n\n\n

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<\/p>\n","protected":false},"excerpt":{"rendered":"

Publications 2011 (165) Kuzmanich, G.; Simoncelli, S.; Gard, M.N.; Sp\u00e4nig, F.; Hoekstra, R.; Guldi, D.M.; Garcia-Garibay, M.A. “Self-Quenching of Benzophenone Excited States in Crystalline Nanoparticles.” J. Am. Chem. Soc., 2011, 133, 17296\u201317306. (164) Kuzmanich, G.; Natarajan, A,; Shi, Y.; Patrick, B.O.; Scheffer, J.R.; Garcia-Garibay, M.A. “Stable Radicals During Photodecarbonylations of Trityl-alkyl Ketones Enable Solid State […]<\/p>\n","protected":false},"author":13,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-1852","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/mgg.chem.ucla.edu\/index.php\/wp-json\/wp\/v2\/pages\/1852","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/mgg.chem.ucla.edu\/index.php\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/mgg.chem.ucla.edu\/index.php\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/mgg.chem.ucla.edu\/index.php\/wp-json\/wp\/v2\/users\/13"}],"replies":[{"embeddable":true,"href":"https:\/\/mgg.chem.ucla.edu\/index.php\/wp-json\/wp\/v2\/comments?post=1852"}],"version-history":[{"count":3,"href":"https:\/\/mgg.chem.ucla.edu\/index.php\/wp-json\/wp\/v2\/pages\/1852\/revisions"}],"predecessor-version":[{"id":1855,"href":"https:\/\/mgg.chem.ucla.edu\/index.php\/wp-json\/wp\/v2\/pages\/1852\/revisions\/1855"}],"wp:attachment":[{"href":"https:\/\/mgg.chem.ucla.edu\/index.php\/wp-json\/wp\/v2\/media?parent=1852"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}