(65) Garcia-Garibay, M.A.; Shin, S.; Sanrame, C. “Engineering Reactions in Crystalline Solids: Prediction of Intramolecular Carbene Rearrangements.”<\/strong><\/a> Tetrahedron 2000, 56, 6729-6737.<\/p>\n\n\n\n (64) Yang, Z.; Garcia-Garibay, M.A. “Engineering Reactions in Crystalline Solids: Radical Pairs in Crystals of Dialkyl 1,3-Acetonedicarboxylates.”<\/strong><\/a> Org. Lett. 2000, 2, 1963-1965.<\/p>\n\n\n\n (75) Ng, D.; Yang, Z.; Garcia-Garibay, M.A. “Engineering Reactions in Crystals: Supression of Photodecarbonylation by Intramolecular &beta-Phenyl Quenching.”<\/strong><\/a> Tetrahedron Lett. 2001, 42, 9113-9116.<\/p>\n\n\n\n (74) Amirsakis, D.G.; Garcia-Garibay, M.A.; Rowan, S.J.; Stoddart, J.F.; White, A.J.P.; Williams, D.J. “Host-Guest Chemistry Aids and Abets a Stereospecific Photodimerization in the Solid State.”<\/strong><\/a> Angew. Chem. 2001, 40, 4256-4261.<\/p>\n\n\n\n (73) Johnson, B.A.; Houk, K.N.; Hu, Y.; Garcia-Garibay, M.A. “Vibrationally Assisted Tunneling in a Hydrogen Atom Transfer Reaction.”<\/strong><\/a> J. Am. Chem. Soc. 2001, 123, 6941-6942.<\/p>\n\n\n\n (72) Yang, Z.; Ng, D.; Garcia-Garibay, M.A. “Engineering Reactions in Crystalline Solids: Photochemical Generation of Secondary and Tertiary Enol Radical Pairs from the Crystalline Ketodiesters.”<\/strong><\/a> J. Org. Chem. 2001, 66, 4468.<\/p>\n\n\n\n (71) Garcia-Garibay, M.A. Book review of Solid State and Surface Photochemistry. Molecular and Supramolecular Photochemistry, Volume 5 by V. Ramamurthy and Kirk S. Schanze. Marcel Dekker: New York and Basel, 2000.<\/strong><\/a> J. Am. Chem. Soc. 2001, 123, 5384-5384.<\/p>\n\n\n\n (70) Levitus, M.; Schmieder, K.; Ricks, H.; Schimizu, K.D.; Bunz, U.H.F.; Garcia-Garibay, M.A. “Steps to Demarcate the Effects of Chromophore Aggregation and Planarization in Poly(phenyleneethynylene)s. 1. Rotationally Interrupted Conjugation in the Excited States of 1,4-Bis(phenylethynyl)benzene.”<\/strong><\/a> J. Am. Chem. Soc. 2001, 123, 4259-4265.<\/p>\n\n\n\n (69) Levitus, M.; Zepeda, G.; Dang, H.; Godinez, C.; Khuong, T.-A.V.; Schmieder, K.; Garcia-Garibay, M.A. “Steps to Demarcate the Effects of Chromophore Aggregation and Planarization in Poly(phenyleneethynylene)s 2. The Photophysics of 1,4-Diethynyl-2-fluorobenzene in Solution and in Crystals.”<\/strong><\/a> J. Org. Chem. 2001, 66, 3188-3195.<\/p>\n\n\n\n (68) Dang, H.; Garcia-Garibay, M.A. “Palladium-Catalyzed Formation of Aceanthrylenes: A Simple Method for Peri-Cyclopentenelation of Aromatic Compounds.”<\/strong><\/a> J. Am. Chem. Soc. 2001, 123, 355-356.<\/p>\n\n\n\n (67) Leyva, E.; Moctezuma, E.; Strouse, J.; Garcia-Garibay, M.A. “Spectrometric and 2D NMR Studies on the Complexation of Chlorophenols with Cyclodextrins.”<\/strong><\/a> J. Inclusion Phenomena 2001, 39, 41-46.<\/p>\n\n\n\n (83) Ng, D.; Yang, Z.; Garcia-Garibay, M.A. “Engineering Reactions in Crystals: gem-Dialkoxy Substitution Enables the Photodecarbonylation of Crystalline 2-Indanone.”<\/strong><\/a> Tetrahedron Lett. 2002, 43, 7063-7066.<\/p>\n\n\n\n (82) Johnson, B.; Kleinman, M.H.; Turro, N.J.; Garcia-Garibay, M.A. “Hydrogen Atom Tunneling in Triplet o-Methylbenzocyloalkanones: Effects of Structure on Reaction Geometry and Excited State Configuration.”<\/a><\/strong> J. Org. Chem. 2002, 67, 6944-6953.<\/p>\n\n\n\n (81) Dominguez, Z.; Dang, H.; Strouse, J.M.; Garcia-Garibay, M.A. “Molecular ‘Compasses’ and ‘Gyroscopes.’ III. Dynamics of a Phenylene Rotor and Clathrated Benzene in a Slipping-Gear Crystal Lattice.”<\/strong><\/a> J. Am. Chem. Soc. 2002, 124, 7719-7727.<\/p>\n\n\n\n (80) Campos, L.M.; Dang, H.; Ng, D.; Yang, Z.; Martinez, H.L.; Garcia-Garibay, M. A. “Engineering Reactions in Crystalline Solids: Predicting Photochemical Decarbonylation from Calculated Thermochemical Parameters.”<\/strong><\/a> J. Org. Chem. 2002, 67, 3749-3754.<\/p>\n\n\n\n (79) Godinez, C.E.; Zepeda, G.; Garcia-Garibay, M.A. “Molecular Compasses and Gyroscopes. II. Synthesis and Characterization of Molecular Rotors with Axially Substituted Bis[2-(9-triptycyl)ethynyl]arenes.”<\/strong><\/a> J. Am. Chem. Soc. 2002, 124, 4701-4707.<\/p>\n\n\n\n (78) Dominguez, Z.; Dang, H.; Strouse, M.J.; Garcia-Garibay, M.A. “Molecular ‘Compasses’ and ‘Gyroscopes.’ I. Expedient Synthesis and Solid State Dynamics of an Open Rotor with a Bis(triarylmethyl) Frame.”<\/strong><\/a> J. Am. Chem. Soc. 2002, 124, 2398-2399.<\/p>\n\n\n\n (77) Schmieder, K.; Levitus, M.; Dang, H.; Garcia-Garibay, M.A. “Photophysical Properties of Coplanar and Twisted 1,4-Bis(9-ethynylanthracenyl)benzene. Rotational Equilibration in the Excited States of Diaryalkynes.”<\/strong><\/a> J. Phys. Chem. A 2002, 105, 1551-1556.<\/p>\n\n\n\n (76) Dang, H.; Levitus, M.; Garcia-Garibay, M.A. “One Step Pd(0)-Catalyzed Synthesis, X-Ray Analysis, and Photophysical Properties of Cyclopent[hi]aceanthrylene: Fullerene-Like Properties in a Nonalternant Cyclopentafused Aromatic Hydrocarbon.”<\/strong><\/a> J. Am. Chem. Soc. 2002, 124, 136-143.<\/p>\n\n\n\n (90) Ellison, M.E.; Ng, D.; Dang, H.; Garcia-Garibay, M.A. “Enantiospecific Synthesis of Vicinal Stereogenic Tertiary and Quaternary Centers by Combination of Configurationally Trapped Radical Pairs in Crystalline Solids.”<\/strong><\/a> Org. Lett. 2003, 5, 2531-2534.<\/p>\n\n\n\n (89) Mortko, C.J.; Dang, D.; Campos. L.M.; Garcia-Garibay, M.A. “H-Abstraction Prevails over &alpha-cleavage in the Solution and Solid State Photochemistry of cis-2,6-di(1-cyclohexenyl)cyclohexanone.”<\/strong><\/a> Tetrahedron Lett. 2003, 44, 6133-6136.<\/p>\n\n\n\n (88) Dominguez, Z.; Khuong, T.A.V.; Sanrame, C.N.; Dang, H.; Nu\u00f1ez, J.E.; Garcia-Garibay, M.A. “Molecular Compasses and Gyroscopes with Polar Rotors: Synthesis and Characterization of Crystalline Forms.”<\/strong><\/a> J. Am. Chem. Soc. 2003, 125, 8827-8837.<\/p>\n\n\n\n (87) Garcia-Garibay, M.A. “Engineering Carbene Rearrangements in Crystals: From Molecular Information to Solid-State Reactivity.”<\/strong><\/a> Acc. Chem. Res. 2003, 36, 491-498.<\/p>\n\n\n\n (86) Garcia-Garibay, M.A.; Campos, L. “Photochemical Decarbonylation of Ketones: Recent Advances and Reactions in Crystalline Solids” in The Handbook for Organic Photochemistry and Photobiology; Horspool, W., Ed.; CRC Press: Boca Raton, FL, 2003.<\/p>\n\n\n\n (85) Sanrame, C.N.; Suhrada, C.P.; Dang, H.; Garcia-Garibay, M.A. “Photochemistry of Crystalline Chlorodiazirines: The Influence of Conformational Disorder and Intermolecular Cl…N=N Interactions on the Solid-State Reactivity of Singlet Chlorocarbenes.”<\/strong><\/a> J. Phys. Chem. A 2003, 107, 3287-3294.<\/p>\n\n\n\n (84) Amirsakis, D.G.; Elizarov, A.M.; Garcia-Garibay, M.A.; Glink, P.T.; Stoddart, J.F.; White, A.J.P.; Williams, D.J. “Diastereospecific Photochemical Dimerization of a Stilbene-Containing Daisy Chain Monomer in Solution as well as in the Solid State.”<\/strong><\/a> Angewandte Chemie, Int. Ed. 2003, 42, 1126-1132.<\/p>\n\n\n\n (95) Khuong, T.A.V.; Sanrame, C.N.; Zepeda, G.; Dang, H.; Bartberger, M.; Houk, K.N.; Garcia-Garibay, M.A. “Crankshaft Motion in a Highly Congested Bis(triarylmethyl)peroxide.”<\/strong><\/a> J. Am. Chem. Soc. 2004, 126, 14778-14786.<\/p>\n\n\n\n (94) Warrier, M.; Lo, M.K.F.; Monbouquette, H.; Garcia-Garibay, M.A. “Photocatalytic Reduction of Aromatic Azides to Amines using CdS and CdSe Nanoparticles.”<\/strong><\/a> Photochem. Photobiol. Sci. 2004, 3, 859-863.<\/p>\n\n\n\n (93) Godinez, C.E.; Zepeda, G.; Mortko, C.J.; Dang, H.; Garcia-Garibay, M.A. “Molecular Crystals with Moving Parts: Synthesis, Characterization, and Crystal Packing of Molecular Gyroscopes with Methyl-Substituted Triptycyl Frames.”<\/strong><\/a> J. Org. Chem. 2004, 69, 1652-1662.<\/p>\n\n\n\n (92) Ng, D.; Yang, Z.; Garcia-Garibay. M.A. “Total Synthesis of (\u00b1)-Herbertenolide by Stereospecific Formation of Vicinal Quaternary Centers in a Crystalline Ketone.”<\/strong><\/a> Org. Lett. 2004, 6, 645-647.<\/p>\n\n\n\n (91) Khuong, T.A.V.; Zepeda, G.; Ruiz, R.; Kahn, S.I.; Garcia-Garibay, M.A. “Molecular Compasses and Gyroscopes: Engineering Molecular Crystals with Fast Internal Rotation.”<\/strong><\/a> Cryst. Growth & Design 2004, 4, 15-18.<\/p>\n\n\n\n (104) Garcia-Garibay, M.A. “Crystalline Molecular Machines: Encoding Supramolecular Dynamics Into Molecular Structure.”<\/strong><\/a> Proc. Natl. Acad. of Sci. 2005, 102, 10793 (invited perspective article). To read this article with Romanian translation, please click here.<\/p>\n\n\n\n (103) Cizmeciyan, D.; Yonutas, H.; Karlen, S.D.; Garcia-Garibay, M.A. “2H NMR and X-ray Diffraction Studies of Methyl Rotation in Crystals of ortho-Methyldibenzocycloalkanones.”<\/strong><\/a> Solid State Nuc. Mag. Res. 2005, 28, 1-8.<\/p>\n\n\n\n (102) Campos, L.M.; Warrier, M.V.; Peterfy, K.; Houk, K.N.; Garcia-Garibay, M.A. “Secondary Alpha Isotope Effects on Deuterium Tunneling in Triplet o-Methylanthrones: Extraordinary Sensitivity to Barrier Width.”<\/strong><\/a> J. Am. Chem. Soc. 2005, 127, 10178-10179.<\/p>\n\n\n\n (101) Horansky, R.D.; Clarke, L.I.; Price, J.C.; Khuong, T.-A.V.; Jarowski, P.D.; Garcia-Garibay, M.A. “Dielectric Response of a Dipolar Molecular Rotor Crystal.”<\/strong><\/a> Phys. Rev. B. 2005, B72, 014302.<\/p>\n\n\n\n (100) Mortko, C.J.; Garcia-Garibay, M.A. “Green Chemistry Strategies Using Crystal-to-Crystal Photoreactions: Stereoselective Synthesis and Decarbonylation of trans-&alpha,&alpha’-Dialkenoylcyclohexanones.”<\/strong><\/a> J. Am. Chem. Soc. 2005, 127, 7994-7995.<\/p>\n\n\n\n (99) Karlen, S.D.; Ortiz, R.; Chapman, O.L.; Garcia-Garibay, M.A. “Effects of Rotational Order on the Solid State Dynamics of Phenylene and Diamantane Rotators.”<\/strong><\/a> J. Am. Chem. Soc. 2005, 127, 6554-6555.<\/p>\n\n\n\n (98) Resendiz, M.J.E.; Garcia-Garibay, M.A. “Hammet Analysis of the Photodecarbonylation in Crystalline 1,3-Diarylacetones.”<\/a><\/strong> Org. Lett. 2005, 7, 371-374.<\/p>\n\n\n\n (97) Karlen, S.D.; Garcia-Garibay, M.A. “Highlighting Gyroscopic Motion in Crystals in 13C CPMAS Spectra by Specific Isotopic Substitution and Restricted Cross Polarization.”<\/strong><\/a> Chem. Commun. 2005, 189-191.<\/p>\n\n\n\n (96) Karlen, S.D.; Kahn, S.I.; Garcia-Garibay, M.A. “Removal of Conflicting Molecular Symmetries Restores a Hexagonal Array of Six-Fold Phenyl Embraces in a bis(Trityl)-Containing Compound. I. Crystals of 1,1,1,6,6,6-Hexaphenyl-2,4-hexadiyne.”<\/strong><\/a> Cryst. Growth & Design 2005, 5, 53-55.<\/p>\n\n\n\n (116) Chin, K.K.; Chuang, S.C.; Hernandez, B.; Selke, M.; Foote, C.S.; Garcia-Garibay, M.A. “Photophysical Properties of a 1,2,3,4,5,6-Hexasubstituted Fullerene Derivative.”<\/strong><\/a> J. Phys. Chem. 2006, 110, 13662-13666.<\/p>\n\n\n\n (115) Campos, L.M.; Mortko, C.J.; Garcia-Garibay, M.A. “Norrish Type I vs. Norrish-Yang Type II in the Solid State Photochemistry of cis-2,6-Di(1-cyclohexenyl)-cyclohexanone: A computational study.” Mol. Cryst. Liq. Cryst. 2006, 456, 15-24.<\/p>\n\n\n\n (114) Karlen, S.D.; Khan, S.I.; Garcia-Garibay, M.A. “Crystalline Molecular Gyroscopes: The Effects of Subtle Molecular Differences on the Crystal Packing of Triphenylmethyl and Triphenylsilyl Stators.”<\/strong><\/a> Mol. Cryst. Liq. Cryst. 2006, 456, 221-230.<\/p>\n\n\n\n (113) Horansky, R.D.; Clarke, L.I.; Winston, E.B.; Price, J.C.; Karlen, S.D.; Jarowski, P.D.; Santillan, R.; Garcia-Garibay, M.A. “Dipolar Rotor-Rotor Interactions in a Difluorobenzene Molecular Rotor Crystal.”<\/strong><\/a> Phys. Rev. B 2006, 74, 054306.<\/p>\n\n\n\n (112) Karlen, S.D.; Godinez, C.E.; Garcia-Garibay, M.A. “Improved Physical Properties and Rotational Dynamics in a Molecular Gyroscope with an Assymmetric Stator Structure.”<\/strong><\/a> Org. Lett. 2006, 8, 2615-2617.<\/p>\n\n\n\n (111) Veerman, M.; Resendiz, M.J.E.; Garcia-Garibay, M.A. “Large-Scale Photochemical Reactions of Nanocrystalline Suspensions: A Promising Green Chemistry Method.”<\/strong><\/a> Org. Lett. 2006, 8, 2615-2617.<\/p>\n\n\n\n (110) Khuong, T.-A.V.; Nu\u00f1ez, J.E.; Godinez, C.E.; Garcia-Garibay, M.A. “Crystalline Molecular Machines: A Quest Toward Solid-State Dynamics and Function.”<\/strong><\/a> Acc. Chem. Res. 2006, 39, 413-422.<\/p>\n\n\n\n (109) Radhakrishnan, C.; Lo, M.K.F.; Garcia-Garibay, M.A.; Warrier, M.V.; Monbouquette, H.G. “Photocatalytic Reduction of an Azide-Terminated Self-Assembled Monolayer Using CdS Quantum Dots.”<\/strong><\/a> Langmuir 2006, 22, 5018-5024.<\/p>\n\n\n\n (108) Choe, T.; Khan, S.I.; Garcia-Garibay, M.A. “Combination Vs. Disproportionation in Dialkyl Biradicals. Selectivity Reversal in a Crystalline Solid.”<\/strong><\/a> Photochem. Photobiol. Sci. 2006, 5, 449-451.<\/p>\n\n\n\n (107) Nu\u00f1ez, J. E.; Khuong, T.-A.V.; Campos, L. M.; Farfan, N.; Dang, H.; Karlen, S. D.; Garcia-Garibay, M.A. “Crystal Phases and Phase Transitions in a Highly Polymorphogenic Solid-State Molecular Gyroscope with meta-Methoxytrityl Frames.”<\/strong><\/a> Cryst. Growth & Design 2006, 6, 866-873.<\/p>\n\n\n\n (106) Mortko, C. J.; Garcia-Garibay, M.A. “Stereospecific Synthesis of Compounds with Adjacent Chiral Quaternary Centers in Solid-to-Solid Reactions.” Topics in Stereochemistry 2006, 25, 205-253.<\/p>\n\n\n\n (105) Karlen, S.D.; Garcia-Garibay, M.A. “Amphidynamic Crystals: Structureal Blueprints for Molecular Machines.”<\/strong><\/a> Topics Curr. Chem. 2006, 262, 179-228.<\/p>\n\n\n\n (126) Resendiz, M.J.E.; Taing, J.; Garcia-Garibay, M.A. “Photodecarbonylation of 1,3-Dithiophenyl Propanone: Using Nanocrystals to Overcome the Filtering Effect of Highly Absorbing Trace Impurities.”<\/strong><\/a> Org. Lett. 2007, 9, 4351-4354.<\/p>\n\n\n\n (125) Garcia-Garibay, M.A. “Molecular Crystals on the Move: From Single-Crystal-to-Single-Crystal Photoreactions to Molecular Machinery.”<\/strong><\/a> Angew Chem. Int. Ed. 2007, 46, 8945-8947.<\/p>\n\n\n\n (124) Grassian, V.H.; Meyer, G.; Abruna, H.; Coates, G.W.; Achenie, L.E.; Allison, T.; Brunschwig, B.; Ferry, J.; Garcia-Garibay, M.A.; Gardea-Torresdey, J.; Grey, C.P.; Hutchison, J.; Li, C.J.; Liotta, C.; Ragauskas, A.; Minteer, S.; Mueller, K.; Roberts, J.; Sadik, O.; Schmel, R.; Schneider, W.; Selloni, A.; Stair, P.; Stewart, J.; Thorn, D.; Tyson, J.; Voelker, B.; White, J.M.; Wood-Black, F. “Chemistry for a Sustainable Future.”<\/strong><\/a> Environ. Sci. Technol. 2007, 41, 3559-3561.<\/p>\n\n\n\n (123) Nunez, J.E.; Natarajan, A.; Khan, S.I.; Garcia-Garibay, M.A. “Synthesis of a Triply Bridged Molecular Gyroscope by a Directed Meridional Cyclization Strategy.”<\/strong><\/a> Org. Lett. 2007, 9, 3559-3561.<\/p>\n\n\n\n (122) Natarajan, A.; Tsai, C.K.; Khan, S.I.; McCarren, P.; Houk, K.N.; Garcia-Garibay, M.A. “The Photoarrangement of &alpha-Santonin is a Single-Crystal-to-Single-Crystal Reaction: A Long Kept Secret in Solid-State Organic Chemistry Revealed.”<\/strong><\/a> J. Am. Chem. Soc. 2007, 129, 9846-9847.<\/p>\n\n\n\n (121) Natarajan, A.; Ng, D.; Yang, Z.; Garcia-Garibay, M.A. “A Green Chemistry Method for the Synthesis of Compounds with Adjacent Quaternary Stereogenic Centers: Parallel Syntheses of (+) and (-)-a-Cuparenone by Radical Combination in Crystalline Solids.” Angew Chem. Int. Ed. 2007, 46, 6485-6487.<\/p>\n\n\n\n (120) Chin, K.K.; Natarajan, A.; Gard, M.N.; Campos, L.M.; Johansson, E.; Shepherd, H.; Garcia-Garibay, M.A. “Pump-Probe Spectroscopy and Circular Dichroism of Nanocrystalline Benzophenone \u2014 Towards Absolute Kinetic Measurements in Solid State Photochemical Reactions.”<\/strong><\/a> Chem. Commun. 2007, 41, 4266-4268.<\/p>\n\n\n\n (119) Jarowski, P.D.; Houk, K.N.; Garcia-Garibay, M.A. “The Importance of Correlated Motions on the Low Barrier Rotational Potentials of Crystalline Molecular Gyroscopes.”<\/strong><\/a> J. Am. Chem. Soc. 2007, 129, 3110-3117.<\/p>\n\n\n\n (118) Campos, L.M.; Garcia-Garibay, M.A. “Reactive Intermediates in Crystals: Form and Function” in Reactive Intermediates; Platz, M.S., Jones, M., Moss, R., Eds.; Hoboken, NJ, 2007.<\/p>\n\n\n\n (117) Khuong, T.-A.V.; Dang, H.; Jarowski, P.D.; Maverick, E.; Garcia-Garibay, M.A. “Rotational Dynamics in a Crystalline Molecular Gyroscope by Variable-Temperature 13C NMR, 2H NMR, X-Ray Diffraction, and Force Field Calculations.”<\/strong><\/a> J. Am. Chem. Soc. 2007, 129, 839-845.<\/p>\n\n\n\n (135) Garcia-Garibay, M.A. “Molecular Machines: Nanoscale Gadgets.”<\/a><\/strong> Nature Materials 2008, 7, 431-432.<\/p>\n\n\n\n (134) Gould, S.L.; Rodriguez, R.B.; Garcia-Garibay, M.A. “Synthesis and Solid State Dynamics of Molecular Dirotors.”<\/a><\/strong> Tetrahedron 2008, 64, 8336-8345.<\/p>\n\n\n\n (133) Chin, K.K.; Trevithick-Sutton, C.C.; McCallum, J.; Jockusch, S.; Turro, N.J.; Scaiano, J.C.; Foote, C.S.; Garcia-Garibay, M.A. “Quantitative Determination of Singlet Oxygen Generated by Excited State Aromatic Amino Acids, Proteins, and Immunoglobulins.”<\/strong><\/a> J. Am. Chem. Soc. 2008, 130, 6912-6913.<\/p>\n\n\n\n (132) Santillan, R.; Karlen, S.D.; Dang, H.; Garcia-Garibay, M.A. “Synthesis and Characterization of Natural Abundance and Isotopically Labeled 1,4-Bis(3,3,3-triphenylpropynyl)-2,3-difluorobenzene. A Molecular Gyroscope with a Polar Rotator.”<\/strong><\/a> J. Mex. Chem. Soc. 2008, 52, 125-129.<\/p>\n\n\n\n (131) Gould, S.L.; Tranchemontagne, D.; Yaghi, O.M.; Garcia-Garibay, M.A. “Amphidynamic Character of Crystalline MOF-5: Rotational Dynamics of Terephthalate Phenylenes in a Free-Volume, Sterically Unhindered Environment.”<\/strong><\/a> J. Am. Chem. Soc. 2008, 130, 3246-3247.<\/p>\n\n\n\n (130) Kuzmanich, G.; Natarajan, A.; Chin, K.K.; Veerman, M.; Mortko, C.J.; Garcia-Garibay, M.A. “Solid-State Photodecarbonylation of Diphenylcyclopropenone: A Quantum Chain Process Made Possible by Ultrafast Energy Transfer.”<\/strong><\/a> J. Am. Chem. Soc. 2008, 130, 1140-1141. (Highlighted in Nature 2008, 451, 897.)<\/p>\n\n\n\n (129) Chin, K.K.; Chuang, S.-C.; Hernandez, B.; Campos, L.M.; Selke, M.; Foote, C.S., Garcia-Garibay, M.A. “Photophysical Properties of Non-Homoconjugated 1, 2-dihydro, 1,2,3,4-tetrahydro and 1,2,3,4,5,6-hexahydro-C60 Derivatives.”<\/strong><\/a> Photochem. Photobiol. Sci. 2008, 1, 49-55.<\/p>\n\n\n\n (128) Resendiz, M.J.E.; Natarajan, A.; Garcia-Garibay, M.A. “Diastereoselective Synthesis and Spin-Dependent Photodecarbonylation of di(3-phenyl-2-pyrrolidinon-3-yl)Ketones: Synthesis of Nonadjacent and Adjacent Stereogenic Quaternary Centers.”<\/strong><\/a> Chem Commun. 2008, 193-195.<\/p>\n\n\n\n (127) Resendiz, M.J.E.; Taing, J.; Khan, S.I.; Garcia-Garibay, M.A. “Unexpected Solid-State Photochemistry of an &alpha-Thiophenyl-&alpha’-Thiophenyl-S,S-dioxo-Subsitituted Ketone.”<\/strong><\/a> J. Org. Chem. 2008, 73, 638-643.<\/p>\n\n\n\n (145) Schlundt, S.; Kuzmanich, G.; Spanich, F.; Rojas, G. de M.; Kovacs, C.; Garcia-Garibay, M.A.; Guldi, D.M.; Hirsch, A. “Dendritic Porphyrin-Fullerene Conjugates: Efficient Light-Harvesting and Charge-Transfer Events.”<\/strong><\/a> Chem. Eur. Journal 2009, 15, 12223-12233.<\/p>\n\n\n\n (144) Rodriguez-Molina, B.; Ochoa, M.E.; Farf\u00e1n, N.; Santillan, R.; Garcia-Garibay, M.A. “Synthesis, Characterization and Rotational Dynamics of Crystalline Molecular Compasses With N-Heterocyclic Rotators.”<\/strong><\/a> J. Org. Chem. 2009, 74, 8554-8565.<\/p>\n\n\n\n (143) Kuzmanich, G.; Gard, M.N.; Garcia-Garibay, M.A. “Photonic Amplification by a Singlet-State Quantum Chain Photodecarbonylation Reaction in Crystalline Diarylcyclopropenones.”<\/strong><\/a> J. Am. Chem. Soc. 2009, 131, 11606-11614.<\/p>\n\n\n\n (142) Hoijemberg, P.A.; Karlen, S.D.; Sanram\u00e9, C.N.; Aramendia, P.F.; Garcia-Garibay, M.A. “Photolysis of an Asymmetrically Substituted Diazene in Solution and in the Crystalline State.”<\/strong><\/a> Photochem. Photobiol. Sc. 2009, 8, 961-969.<\/p>\n\n\n\n (141) Godinez, C.E.; Garcia-Garibay, M.A. “Engineering Crystal Packing and Internal Dynamics in Molecular Gyroscopes by Refining Their Components. Fast Exchange of a Phenylene Rotator by 2H NMR.”<\/strong><\/a> Cryst. Growth & Design 2009, 9, 3124-3128.<\/p>\n\n\n\n (140) Mitsumori, T.; Campos, L.M.; Garcia-Garibay, M.A.; Wudl, F.; Sato, H.; Sato, Y. “Synthesis, Properties, and LED Performance of Highly Luminescent Metal Complexes Containing Indolizino[3,4,5-ab]isoindoles.”<\/strong><\/a> J. Mat. Chem. 2009, 19, 5826-5836.<\/p>\n\n\n\n (139) Resendiz, M.J.E.; Family, F.; Fuller, K.; Campos, L.M.; Khan, S.I.; Lebedeva, N.V.; Forbes, M.D.E.; Garcia-Garibay, M.A. “Radical Reactions with Double Memory of Chirality (2MOC) for the Enantiospecific Synthesis of Adjacent Stereogenic Quaternary Centers in Solution: Cleavage and Bonding Faster than Radical Rotation.”<\/strong><\/a> J. Am. Chem. Soc. 2009, 131, 8425-8433.<\/p>\n\n\n\n (138) Amboya, A.; Nguyen, T.; Huynh, H.T.; Brown, H.; Ratliff, G.; Yonutas, H.; Cizmeciyan, D.; Natarajan, A.; Garcia-Garibay, M.A. “Radical Pairs with Rotational Fluidity in the Photochemical Reaction of Acetophenone and Cyclohexane in the Zeolite NaY: A 13C CPMAS NMR and Product Analysis Study.”<\/strong><\/a> Org. Biomol. Chem. 2009, 7, 2322-2326.<\/p>\n\n\n\n (137) Family, F.; Garcia-Garibay, M.A. “Photodecarbonylation of Ketodiacids as Ammonium Salts: Efficient Formation of C-C Bonds Between Adjacent Quaternary Centers in the Crystalline State.”<\/strong><\/a> J. Org. Chem. 2009, 74, 2476-2480.<\/p>\n\n\n\n (136) Garcia-Garibay, M.A.; Dang, H.D. “Photochemical Generation, Intramolecular Reactions, and Spectroscopic Detection of Oxonium Ylide and Carbene Intermediates in a Crystalline ortho-(1,3-Dioxolan-2-yl)-diaryldiazomethane.”<\/strong><\/a> Org. Biomol. Chem. 2009, 1106-1114.<\/p>\n\n\n\n (153) Garcia-Garibay, M.A. “The Entropic Enlightenment of Organic Photochemistry: Strategic Modifications of Intrinsic Decay Pathways Using an Information-Based Approach.”<\/strong><\/a> Photochem. & Photobiol. Sci., 2010, 9, 1574-1588 (invited article).<\/p>\n\n\n (152) Karlen, S.D.; Reyes, H.; Taylor, R.E.; Khan, S.I.; Hawthorne, M.F.; Garcia-Garibay, M.A. “Symmetry and Dynamics of Molecular Rotors in Amphidynamic Molecular Crystals.”<\/strong><\/a> Proc. Nat. Acad. Sci. USA, 2010, 107, 14973.<\/p>\n\n\n (151) Bouit, P.-A.; Spanig, F.; Kuzmanich, G.; Krokos, E.; Oelsner, C.; Garcia-Garibay, M.A.; Delgado, J.L.; Martin, N.; Guldi, D.M. “Efficient Utilization of Higher Lying Excited States to Trigger Change Transfer Events.”<\/strong><\/a> Chem. Eur. Journal, 2010, 16, 9638-9645.<\/p>\n\n\n (150) Shiraki, S.; Garcia-Garibay, M.A. “Carbon-Carbon Bond Formation By Photoelimination of Small Molecules in Solution and in Crystals” in Handbook of Synthetic Photochemistry, Albini, A., Fagnini, M. Eds., Wiley-VCH, Weinheim, 2010, pp. 25-66.<\/p>\n\n\n (149) Rodriguez-Molina, B.; Pozos, A.; Cruz, R.; Romero, M.; Flores, B.; Farfan, N.; Santillan, R.; Garcia-Garibay, M.A. “Synthesis and solid state characterization of molecular rotors with steroidal stators: ethisterone and norethisterone.” Org. Biomol. Chem. 2010, 8, 2993-3000.<\/p>\n\n\n (148) O’Brien, Z.J.; Karlen, S.D.; Khan, S.; Garcia-Garibay, M.A. “Solid State Molecular Rotors with Perdeuterated Stators: Mechanistic Insights from Biphenylene Rotational Dynamics in Ordered and Disordered Crystal Forms.”<\/strong><\/a> J. Org. Chem., 2010, 75, 2482-2491.<\/p>\n\n\n
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